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| 1792 | Godoy, Manuel de |  |
| Appointed Prime Minister of Spain |
| 1843 | Gonzalez Bravo, Luis | |
| Appointed Prime Minister of Spain, 1st term |
| 1868 | Gonzalez Bravo, Luis | |
| Appointed Prime Minister of Spain, 2nd term |
| 1875 | Canovas del Castillo, Antonio | |
| Appointed Prime Minister of Spain, 1st term |
| 1879 | Canovas del Castillo, Antonio | |
| Appointed Prime Minister of Spain, 2nd term |
| 1884 | Canovas del Castillo, Antonio | |
| Appointed Prime Minister of Spain, 3rd term |
| 1890 | Canovas del Castillo, Antonio | |
| Appointed Prime Minister of Spain, 4th term |
| 1895 | Canovas del Castillo, Antonio | |
| Appointed Prime Minister of Spain, 5th term |
| 1913 | Dato Iradier, Eduardo | |
| Appointed Prime Minister of Spain, 1st term |
| 1917 | Dato Iradier, Eduardo | |
| Appointed Prime Minister of Spain, 2nd term |
| 1920 | Dato Iradier, Eduardo | |
| Appointed Prime Minister of Spain, 3rd term |
| 1931 | Alcala Zamora, Niceto | |
| April Appointed Prime Minister of Spain, forms a provisional government |
| 1931 | Azana, Manuel | |
| Appointed Prime Minister of Spain, first Prime Minister of the Second Republic |
| 1931 | Diez, Manuel Azana y | |
| Appointed Prime Minister of Spain, 1st term |
| 1931 | Garcia, Alejandro Lerroux y | |
| Appointed Prime Minister of Spain, 1st term |
| 1933 | Barrio, Diego Martinez y | |
| Appointed Prime Minister of Spain, 1st term, caretaker |
| 1933 | Garcia, Alejandro Lerroux y | |
| Appointed Prime Minister of Spain, 2nd term |
| 1933 | Lerroux, Alejandro | |
| 19th Nov Appointed Prime Minister of Spain |
| 1934 | Garcia, Alejandro Lerroux y | |
| Appointed Prime Minister of Spain, 3rd term |
| 1934 | Ibanez, Ricardo Samper | |
| Appointed Prime Minister of Spain |
| 1934 | Lerroux, Alejandro | |
| 1st Oct Appointed Prime Minister of Spain |
| 1934 | Samper, Ricardo | |
| May Apponted Prime Minister of Spain |
| 1935 | Chapaprieta, Joaquin | |
| 25th Sep Appointed Prime Minister of Spain |
| 1935 | Terragosa, Joaquin Chapaprieta y | |
| Appointed Prime Minister of Spain |
| 1935 | Valladares, Manuel Portela | |
| 14th Dec Appointed Prime Minister of Spain |
| 1936 | Diez, Manuel Azana y | |
| Appointed Prime Minister of Spain, 2nd term |
| 1936 | Giral, Jose | |
| 19th July Appointed Prime Minister of Spain |
| 1936 | Largo Caballero, Francisco | |
| 4th Sep Appointed Prime Minister of Spain |
| 1936 | Pereira, Jose Giral y | |
| Appointed Prime Minister of Spain |
| 1936 | Quiroga, Santiago Casares | |
| Appointed Prime Minister of Spain |
| 12th May Appointed Prime Minister of Spain |
| 1937 | Negrin, Juan | |
| 17th May Appointed Prime Minister of Spain |
| 1973 | Arias Navarro, Carlos | |
| Appointed Prime Minister of Spain following the assassination of Carrero Blanco |
| 1973 | Blanco, Louis Carrero | |
| Appointed Prime Minister of Spain |
| 1973 | Miranda, Torcuato Fernandez | |
| Appointed Prime Minister of Spain |
| 1973 | Navarro, Carlos Artos | |
| Appointed Prime Minister of Spain |
| 1976 | Gonzalez, Adolfo Suarez | |
| Appointed Prime Minister of Spain |
| 1976 | Suerez, Adolfo | |
| 3rd July Appointed Prime Minister of Spain by King Juan Carlos |
| 1981 | Bustelo, Leopold Calvo-Soleto y | |
| Appointed Prime Minister of Spain |
| 1981 | Sotelo y Bustelo, Leopoldo Calvo | |
| Feb Appointed Prime Minister of Spain |
| 1982 | Gonzalez Marquez, Felipe | |
| Appointed Prime Minister of Spain |
| 1982 | Marquez, Felipe Gonzalez | |
| Appointed Prime Minister of Spain |
| 1996 | Aznar, Jose Maria | |
| Appointed Prime Minister of Spain |
